119010-67-2Relevant academic research and scientific papers
Organothio groups as electroauxiliaries: Electrooxidative inter- and intramolecular carbon-carbon bond formation
Yoshida,Sugawara,Kise
, p. 3157 - 3160 (2007/10/03)
Anodic oxidation of α-organothio ethers results in the cleavage of the carbon-sulfur bone and the introduction of carbon nucleophiles onto the carbon, suggesting the effectiveness of organothio groups as electroauxiliaries.
Reductive Lithiation Mediated Anionic Cyclizations and -Sigmatropic Rearrangements
Broka, Chris A.,Shen, Tong
, p. 2981 - 2984 (2007/10/02)
The anionic cyclization of several α-alkoxylithiums derived by transmetalation from their corresponding (tributylstannyl)methyl ethers is described.The resulting 2,4-disubstituted tetrahydrofurans are primarily the cis stereoisomers.It is also shown that
