119021-64-6Relevant academic research and scientific papers
DIASTEREOSPECIFIC ADDITION OF ORGANOMETALLICS TO (S)-2-ALKOXY-1-(1,3-DITHIAN-2-YL)-1-PROPANONES AND ITS APPLICATION TO THE SYNTHESIS OF (-)-TRACHELANTHIC ACID.
Sato, Toshio,Kato, Ryoji,Gokyu, Kenji,Fujisawa, Tamotsu
, p. 3955 - 3958 (2007/10/02)
Nucleophilic addition of organometallics to (S)-2-alkoxy-1-(1,3-dithian-2-yl)-1-propanones afforded preferentially (1R,2S)-2-alkoxy-1-alkyl-1-(1,3-dithian-2-yl)-1-propanols.The utility of the present reaction was demonstrated in the synthesis of (2R,3S)-t
