1190398-38-9Relevant academic research and scientific papers
Pd-Catalyzed allylic C-H activation to seven-memberedN,O-heterocycles
Saá, Carlos,Varela, Jesús A.,Velasco-Rubio, álvaro
supporting information, p. 10915 - 10918 (2021/10/22)
Pd-catalyzed allylic C-H activation of simple olefins allows an easy entry to seven-memberedN,O-heterocycles such as 1,4-benzoxazepines (1,4-BZOs), 1,4-benzodiazepinones (1,4-BZDs) and 1,4-oxazepanes in good to excellent yields. Straightforward derivatiza
Ring opening of cyclic N,O-acetals with allyltrimethylsilane under Lewis acidic conditions
Bates, Roderick W.,Lu, Yongna,Cai, Melody Peiling
experimental part, p. 7852 - 7858 (2009/12/26)
Five and six-membered cyclic N,O-acetals with N-carboxyalkyl and sulfonyl groups undergo clean and high yielding ring opening with allyltrimethylsilane in the presence of strong Lewis acids to give homoallylic amine derivatives.
