119139-99-0Relevant academic research and scientific papers
Diastereoselective Intramolecular Hydride Transfer Triggered by Electrophilic Halogenation of Aryl Alkenes
Wang, Bin,Gandamana, Dhika Aditya,León Rayo, David Fabian,Gagosz, Fabien,Chiba, Shunsuke
, p. 9179 - 9182 (2019/11/14)
Diastereoselective hydride transfer could be triggered by electrophilic halogenation (bromination or fluorination) of homoallylic alcohol O-Bn ethers. The resulting diastereomerically enriched haloalkyl alcohols underwent subsequent intramolecular nucleop
DIASTEREOSELECTIVE SYNTHESIS OF HEXAHYDRO-3H-OXAZOLOPYRIDIN-3-ONE DERIVATIVES BY CYCLIZATION OF α-ACYLAMINORADICAL-OLEFIN SYSTEM
Kano, Shinzo,Yuasa, Yoko,Asami, Kenji,Shibuya, Shiroshi
, p. 1437 - 1444 (2007/10/02)
The substituent effect in α-acylaminoradical-olefin cyclization was examined.Treatment of 4-phenylthiooxazolidin-2-ones (10a-f) with tri-n-butyltin hydride in the presence of AIBN yielded 6,7-cis-6,8a-trans-6-alkyl-7-arylhexahydrooxazolopyridin-3-ones (11a-f), respectively, with high diastereoselectivity.
