1191391-91-9

Basic information

• Product Name: tert-butyl((2,5-dimethoxybenzyl)oxy)diphenylsilane
• Synonyms: tert-butyl((2,5-dimethoxybenzyl)oxy)diphenylsilane
• CAS NO: 1191391-91-9
• Molecular Weight: 406.597
• Mol File: 1191391-91-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-butyl((2,5-dimethoxybenzyl)oxy)diphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl((2,5-dimethoxybenzyl)oxy)diphenylsilane(1191391-91-9)
• EPA Substance Registry System: tert-butyl((2,5-dimethoxybenzyl)oxy)diphenylsilane(1191391-91-9)

Safety Data

• Hazardous Substances Data: 1191391-91-9(Hazardous Substances Data)

Upstream product

• 93-02-7 2,5-dimethoxybenzaldehyde 
• 33524-31-1 2,5-dimethoxybenzyl alcohol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 1191391-89-5 3-(tert-butyldiphenylsiloxymethyl)-4,4-dimethoxycyclohexa-2,5-dienone 

Relevant articles and documents

Toward the Stereoselective Synthesis of Arthrobotrisin A: Fragment Synthesis and Coupling Studies

A route towards the stereocontrolled synthesis of arthrobotrisin A based on a Nozaki-Hiyama-Kishi (NHK) coupling strategy was developed. Highlights of the fragment synthesis include enzyme-catalyzed kinetic resolution, Negishi carbometalation-iodination, quinone formation through oxidation with hypervalent iodine, chiral oxazaborolidine-catalyzed asymmetric Diels-Alder reaction with cyclopentadiene, regio- and stereoselective epoxidation, Noyori reduction, retro-Diels-Alder reaction, diastereoselective Luche reduction, and, finally, a Nozaki-Hiyama-Kishi (NHK) coupling of the vinyl iodide fragment.