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119145-82-3

(E)-(η1-C6(CD3)5CD2)Ta(CH=CD(CMe3))(2,6-OC6H3(i-Pr)2)2Cl is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 119145-82-3 Structure

  • Basic information

    1. Product Name: (E)-(η1-C6(CD3)5CD2)Ta(CH=CD(CMe3))(2,6-OC6H3(i-Pr)2)2Cl
    2. Synonyms:
    3. CAS NO:119145-82-3
    4. Molecular Formula:
    5. Molecular Weight: 833.211
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 119145-82-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (E)-(η1-C6(CD3)5CD2)Ta(CH=CD(CMe3))(2,6-OC6H3(i-Pr)2)2Cl(CAS DataBase Reference)
    10. NIST Chemistry Reference: (E)-(η1-C6(CD3)5CD2)Ta(CH=CD(CMe3))(2,6-OC6H3(i-Pr)2)2Cl(119145-82-3)
    11. EPA Substance Registry System: (E)-(η1-C6(CD3)5CD2)Ta(CH=CD(CMe3))(2,6-OC6H3(i-Pr)2)2Cl(119145-82-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 119145-82-3(Hazardous Substances Data)

119145-82-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 119145-82-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,9,1,4 and 5 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 119145-82:
(8*1)+(7*1)+(6*9)+(5*1)+(4*4)+(3*5)+(2*8)+(1*2)=123
123 % 10 = 3
So 119145-82-3 is a valid CAS Registry Number.

119145-82-3Downstream Products

119145-82-3Relevant articles and documents

Evidence for Intramolecular C-H Bond Activation and the Formation of a "Tucked-In" Complex of Hexamethylbenzene at a Tantalum(III) Center

Ballard, Kurt R.,Gardiner, Ian M.,Wigley, David, E.

, p. 2159 - 2162 (2007/10/02)

The reactions of the d2 tantalum complex (η6-C6Me6)Ta(OR)2Cl (1, OR=2,6-diisopropylphenoxide) with 3,3-dimethyl-1-butyne and 3-chloropropene provide the η1-pentamethylbenzyl compounds (E)-(η1-C6Me5CH2)Ta(CH=CH-(CMe3))(OR)2Cl (3) and (η1-C6Me5CH2)Ta(CH2CH2CH2Cl)(OR)2Cl (5), respectively.Both complexes are proposed to have arisen through the intermediacy of an unprecedented d0 "tucked-in" hexamethylbenzene compound, viz. (η6,η1-C6Me5CH2)Ta(H)(OR)2Cl (4).The intramolecular metalation of a methyl C-H bond in 1 and the existence of a hydride intermediate are also inferred from various deuterium labeling and kinetics studies.The metalated hexamethylbenzene can be functionalized selectively as demonstrated in the iodination of 3 to form C6(CH3)5CH2I and (E)-CHI=CH(CMe3).

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