1192279-36-9Relevant academic research and scientific papers
Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes
Dogan, Oeznur,Guerbuez, Nevin,Oezdemir, Ismail,Cetinkaya, Bekir,Sahin, Onur,Bueyuekguengoer, Orhan
, p. 7087 - 7093 (2009)
The reaction of Pd(OAc)2 with 1-(benzhydryl)-3-(alkyl) benzimidazolium salts 1a-d yields trans-bis[1-(benzhydryl)-3-(alkyl) benzimidazolin-2-ylidene]dibromopalladium(II) complexes (2a-d) which were characterized by elemental analysis, NMR spectroscopy and the molecular structures of 2b, and 2d were determined by X-ray crystallography. The catalytic activity of PdBr2bis(benzimidazolin-2-ylidene) complexes 2a-d was evaluated in the direct arylation reaction of benzothiazole with bromobenzene derivatives.
