1192371-32-6

Basic information

• Product Name: 1,3-di(2-anisidyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepinium iodide
• Synonyms: 1,3-di(2-anisidyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepinium iodide
• CAS NO: 1192371-32-6
• Molecular Weight: 438.308
• Mol File: 1192371-32-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-di(2-anisidyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepinium iodide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-di(2-anisidyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepinium iodide(1192371-32-6)
• EPA Substance Registry System: 1,3-di(2-anisidyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepinium iodide(1192371-32-6)

Safety Data

• Hazardous Substances Data: 1192371-32-6(Hazardous Substances Data)

Upstream product

• 628-21-7 1,4-Diiodobutane 
• 68012-05-5 N,N'-bis(2-methoxyphenyl)formamidine 

Downstream Products

• 1192371-06-4 1,3-di-(2-anisidyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepinium tetrafluoroborate 

Relevant articles and documents

Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis

The synthesis of new functionalised 6- and 7-membered NHC (N-heterocyclic carbene) precursors bearing anisidyl or pyridine N-substituents, both symmetrically and non-symmetrically substituted is reported. Their corresponding rhodium(i) and iridium(i) complexes, M(COD)(NHC)Cl, were also prepared and characterised. The unusual Rh(iii)/Rh(i) salt, [Rh(η2-NHC-py) 2Cl2][Rh(COD)Cl2], was obtained with one of the pyridyl-functionalised NHC ligands. Single-crystal X-ray analyses have been obtained for the majority of the complexes and NHC salts. The activity of these complexes was tested in the hydrogenation of a range of substrates with molecular hydrogen, including 1-cyclooctadiene and 2-methyl styrene, where they show enhanced activity and stability in comparison to non-functionalised NHC analogues, operating under exceptionally mild conditions (ambient temperature and atmospheric pressure).