119239-01-9Relevant academic research and scientific papers
PALLADIUM-CATALYZED ASYMMETRIC SYNTHESIS OF AXIALLY DISSYMMETRIC 4-t-BUTYL-ALKYLIDENECYCLOHEXANE DERIVATIVE
Fiaud, J. C.,Legros, J. Y.
, p. 2959 - 2962 (1988)
Cis- and trans-4-tert-butyl-1-vinylcyclohexyl acetates gave optically active ( up to 40 percent ee) dimethyl 2-(4-tert-butylcyclohexylidene)methylmalonate through Pd-catalyzed reaction of sodium dimethylmalonate in the presence of chiral phosphines.
Palladium-catalyzed asymmetric synthesis of axially chiral molecules
Fiaud, J. C.,Legros, J. Y.
, p. 383 - 396 (2007/10/02)
The asymmetric synthesis of chiral 3-alkylidene bicyclooctane and 4-substituted 1-alkylidene cyclohexane systems has been carried out (in up to 40percent ee) by the palladium-catalyzed reaction of allylic acetates with sodium dimethyl malonate or m
