PALLADIUM-CATALYZED ASYMMETRIC SYNTHESIS OF AXIALLY DISSYMMETRIC 4-t-BUTYL-ALKYLIDENECYCLOHEXANE DERIVATIVE

DOI: 10.1016/0040-4039(88)85057-3

Source and publish data:

Tetrahedron Letters p. 2959 - 2962 (1988)

Update date:2022-09-26

Topics:

Authors:

Fiaud, J. C.

Legros, J. Y.

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Article abstract of DOI:10.1016/0040-4039(88)85057-3

Cis- and trans-4-tert-butyl-1-vinylcyclohexyl acetates gave optically active ( up to 40 percent ee) dimethyl 2-(4-tert-butylcyclohexylidene)methylmalonate through Pd-catalyzed reaction of sodium dimethylmalonate in the presence of chiral phosphines.

Full text of DOI:10.1016/0040-4039(88)85057-3

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