119239-74-6Relevant academic research and scientific papers
Cluster-bound ylides derived from CCO. Conversion of [Fe2Co(CO)9(CCO)]- to [Fe2Co(CO)9(CPR3)]-
Ching, Stanton,Sabat, Michal,Shriver, Duward F.
, p. 1047 - 1058 (2008/10/08)
The ketenylidene-containing cluster [PPN][Fe2Co(CO)9(CCO)] (1) reacts with a variety of simple phosphines to produce cluster-bound phosphorus ylides. The reactions proceed by a two-step process in which initial substitution at the Co
