1192469-23-0Relevant articles and documents
A new BINOL-derived chiral bifunctional phosphine organocatalyst: Preparation and application in asymmetric (Aza)-morita-baylis-hillman reactions
Wang, Chunzhang,Wang, Lijun,Zeng, San,Xu, Silong,He, Zhengjie
, p. 1548 - 1554 (2013)
A new BINOL-derived chiral bifunctional phosphine has been designed and successfully prepared, which features a cyclic substructure of 1,3,5-diazaphosphinane. This chiral phosphine possesses good air stability in solid state, and it can be conveniently us
Chiral phosphinothiourea-catalyzed asymmetric Morita-Baylis-Hillman reactions of acrylates with aromatic aldehydes
Yuan, Kui,Song, Hong-Liang,Hu, Yinjun,Wu, Xin-Yan
experimental part, p. 8185 - 8190 (2010/01/06)
A series of chiral bifunctional phosphinothioureas were synthesized and applied to the enantioselective Morita-Baylis-Hillman reaction of aromatic aldehydes with acrylates. In the presence of 8 mol % of organocatalyst 2e, the Baylis-Hillman adducts were o
Valine-derived phosphinothiourea as organocatalyst in enantioselective Morita-Baylis-Hillman reactions of acrylates with aromatic aldehydes
Gong, Jing-Jing,Yuan, Kui,Wu, Xin-Yan
experimental part, p. 2117 - 2120 (2010/03/04)
A new type of chiral bifunctional phosphinothiourea derived from l-valine is synthesized and used as an organocatalyst in the enantioselective Morita-Baylis-Hillman reaction of aromatic aldehydes with acrylates. The desired products were obtained in good
