1192620-83-9 Usage
Uses
Used in Pharmaceutical Industry:
N-[3-(n6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN')-ethyl-2-aMino-(kN)]rutheniuM(II) (R,R)-Teth-TsDpen RuCl WILLS CATALYST is utilized as a key component in the synthesis of chiral pharmaceuticals. Its ability to catalyze asymmetric hydrogenation reactions allows for the production of enantiomerically pure compounds, which are essential in the development of drugs with specific biological activities and reduced side effects.
Used in Agrochemical Industry:
In the agrochemical sector, this ruthenium-based catalyst serves as a catalyst for the synthesis of chiral pesticides and agrochemicals. The asymmetric hydrogenation reactions it promotes enable the production of enantiomerically pure active ingredients, which can improve the efficacy and selectivity of these compounds, reducing potential environmental impacts.
Used in Materials Science:
N-[3-(n6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN')-ethyl-2-aMino-(kN)]rutheniuM(II) (R,R)-Teth-TsDpen RuCl WILLS CATALYST is also employed in the field of materials science for the synthesis of chiral materials with specific properties. These materials can be used in various applications, such as sensors, catalysts, and optical devices, where the chirality of the material plays a crucial role in its performance.
Overall, the N-[3-(n6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN')-ethyl-2-aMino-(kN)]rutheniuM(II) (R,R)-Teth-TsDpen RuCl WILLS CATALYST is a highly valuable compound in the realm of organic synthesis, with applications spanning across multiple industries due to its unique ability to facilitate asymmetric hydrogenation reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 1192620-83-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,9,2,6,2 and 0 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1192620-83:
(9*1)+(8*1)+(7*9)+(6*2)+(5*6)+(4*2)+(3*0)+(2*8)+(1*3)=149
149 % 10 = 9
So 1192620-83-9 is a valid CAS Registry Number.
1192620-83-9Relevant academic research and scientific papers
Hayes, Aidan M.,Morris, David J.,Clarkson, Guy J.,Wills, Martin
, p. 7318 - 7319 (2005)
Ruthenium dimer 6 (readily available in two steps from TsDPEN) is converted directly to monomeric asymmetric transfer hydrogenation catalyst 3 in situ under the conditions employed for ketone reduction. Catalyst 3 is a significantly more active catalyst f
Synthesis and catalytic applications of an extended range of tethered ruthenium(II)/η6-arene/diamine complexes
Hodgkinson, Roy,Jurk, Vclav,Zanotti-Gerosa, Antonio,Nedden, Hans Günter,Blackaby, Andrew,Clarkson, Guy J.,Wills, Martin
supporting information, p. 5517 - 5524 (2015/02/19)
A series of novel enantiopure Ru(II) complexes containing a chiral diamine and η6-arene connected by a tethering group have been prepared and were evaluated in the asymmetric reductions of a range of ketones. Changes to the level of steric hindrance and the addition of an electron-withdrawing functionality on the sulfonyl group have a significant effect on the reactivity and enantioselectivity of the catalysts.
