119286-07-6Relevant academic research and scientific papers
Synthesis of β-dihydroxysulfides by cleavage of epoxides using quaternized amino-functionalized cross-linked polyacrylamide as a new polymeric phase transfer catalyst
Mahdavi,Tamami
, p. 1929 - 1936 (2005)
Poly[N-(2-aminoethyl)acrylamido]trimethyl ammonium halide resin was developed as a new solid-liquid phase transfer catalyst. This quaternized polyacrylamide catalyzed regioselective ring opening of epoxide by Na 2S to obtain bis[β-hydroxyalkyl]
Simple and highly efficient catalyst- and waste-free ring opening of epoxides with Na2S in water
Azizi, Najmedin,Akbari, Elham,Ebrahimi, Frough,Saidi, Mohammad R.
experimental part, p. 323 - 326 (2011/08/03)
Water was found to be a highly efficient and green catalyst and solvent for ring-opening reaction of epoxides with Na2S at room temperature to give substituted bis(hydroxyethyl)thioethers in high yields.
Silica gel-promoted synthesis of 1,4-oxathiane derivatives from β,β′-dichloro sulfides
Minakata, Satoshi,Mihara, Masatoshi,Sugoh, Nozomu,Komatsu, Mitsuo
, p. 133 - 137 (2007/10/03)
Treatment of bis(2-chloro-2-phenylethyl) sulfide, prepared from SCl2 and styrene, with commercially available silica gel in n-hexane and benzene at 30 °C for 6 h gave 2,6-diphenyl-1,4-oxathiane in quantitative yield. The cyclization was success
Triphenylsilanethiol: A solid H2S equivalent in the ring opening of epoxides
Brittain, John,Gareau, Yves
, p. 3363 - 3366 (2007/10/02)
Triphenylsilanethiol, a white crystalline solid, can be used in the opening of epoxides to form β-hydroxymercaptans or β-dihydroxysulfides.
