119293-48-0Relevant articles and documents
Studies on the oxidative N-demethylation of atropine, thebaine and oxycodone using a FeIII-TAML catalyst
Do Pham, Duy D.,Kelso, Geoffrey F.,Yang, Yuanzhong,Hearn, Milton T.W.
, p. 1399 - 1409 (2014)
The reaction pathway and selectivity of the oxidative N-demethylation of the alkaloid atropine with H2O2 using a Fe III-TAML catalyst has been investigated. The conversion of atropine in ethanol with aqueous H2O
ELECTRON-TRANSFER ACTIVATION. SALT EFFECTS ON THE PHOTOOXADIDATION OF TERTIARY AMINES : A USEFUL N-DEMETHYLATION METHOD
Santamaria, J.,Ouchabane, R.,Rigaudy, J.
, p. 3977 - 3980 (2007/10/02)
Photooxidation of tertiary methylamines sensitized by electron acceptors like 9,10-dicyanoanthracene is shown to proceed by two distinct ways depending on the presence of added salts.In the absence of added salt both nor and N-formyl compounds were obtained while with added salt the nor-derivative is obtained highly efficiently.
