119405-00-4Relevant academic research and scientific papers
Reactions of α-Diazoketones with Olefinic Compounds in Presence of Catalysts and Related Studies
Podder, Ranjan Kumar,Sarkar, Tarani Kanta,Sarkar, Ranjit Kumar,Ray, Suvas C.
, p. 217 - 224 (2007/10/02)
A relatively stable cyclopropane adduct is produced by trapping ketocarbenes in olefin.The reactivities of ketocarbenes prepared thermally from different α-diazoketones and of the olefin substrates, and the effect of different catalysts and solvents are some of the parameters which have a pronounced effect on the yield of the products.Besides the cyclopropane adducts some side products have also been isolated and characterized.
