119407-12-4Relevant academic research and scientific papers
Highly selective Friedel-Crafts monoalkylation using micromixing
Suga, Seiji,Nagaki, Aiichiro,Yoshida, Jun-Icih
, p. 354 - 355 (2003)
Highly selective Friedel-Crafts monoalkylation of aromatic compounds with N-acyliminium ions has been achieved by efficient 1:1 mixing using a multilamination-type micromixer.
Control of extremely fast competitive consecutive reactions using micromixing. Selective Friedel-Crafts aminoalkylation
Nagaki, Aiichiro,Togai, Manabu,Suga, Seiji,Aoki, Nobuaki,Mae, Kazuhiro,Yoshida, Jun-Ichi
, p. 11666 - 11675 (2005)
Friedel-Crafts reactions of aromatic and heteroaromatic compounds with an N-acyliminium ion pool were studied. The reaction of 1,3,5-trimethylbenzene in a batch reactor gave rise to the selective formation of a monoalkylation product (69%). Presumably, th
ELECTROCHEMICAL OXIDATION OF α-SILYLCARBAMATES
Yoshida, Jun-ichi,Isoe, Sachihiko
, p. 6621 - 6624 (2007/10/02)
α-Silyl group activates carbamates toward electrochemical oxidation which results in facile cleavage of carbon-silicon bond and regioselective introduction of methanol at α-carbon.
