1194234-13-3

Basic information

• Product Name: methyl 6-O-(4-O-isobutyryl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside
• CAS NO: 1194234-13-3
• Molecular Weight: 696.792
• Mol File: 1194234-13-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 6-O-(4-O-isobutyryl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-O-(4-O-isobutyryl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside(1194234-13-3)
• EPA Substance Registry System: methyl 6-O-(4-O-isobutyryl-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside(1194234-13-3)

Safety Data

• Hazardous Substances Data: 1194234-13-3(Hazardous Substances Data)

Upstream product

• 1012045-70-3 methyl 2,3,4-tri-O-benzyl-6-O-(β-D-glucopyranosyl)-α-D-glucopyranoside 
• 6482-34-4 bis-2-propyl carbonate 

Relevant articles and documents

Functional group tolerance in organocatalytic regioselective acylation of carbohydrates

(Chemical Equation Presented) Organocatalytic regioselective acylation of mono- and disaccaharides with various functionalized acid anhydrides has been developed. Acylation of octyl β-D-glucopyranoside with acid anhydrides derived from R-amino acids, cinnamic acid, and gallic acid took place at C(4)-OH with 67-94% regioselectivity in the presence of catalyst 1. Regioselective acylation of disaccharides with functionalized acid anhydrides was also achieved with 78-94% selectivity. Especially, a disaccharide with seven free hydroxy groups (X = OH, R′ = H) underwent acylation at C(4)-OH with 78% regioselectivity in the presence of 1. Thus, functional group tolerance in the regioselective acylation catalyzed by 1 was found to be high.