1194545-71-5Relevant academic research and scientific papers
Novel chiral bisformamide-promoted asymmetric allylation of benzaldehyde with allyltrichlorosilane
Ishimaru, Kaori,Ono, Kaori,Tanimura, Yuya,Kojima, Takakazu
scheme or table, p. 3627 - 3634 (2011/10/09)
Novel chiral bisformamides have been prepared from (R,R)-1,2- cyclohexanediamine and utilized as Lewis bases in the asymmetric allylation of benzaldehyde with allyltrichlorosilane. The reaction in the presence of Lewis base 1i gave an 83:17 enantiomeric r
Supramolecular-directed chiral induction in biaryl derivatives
Etxebarria,Degenbeck,Felten,Serres,Nieto,Vidal-Ferran
supporting information; experimental part, p. 8794 - 8797 (2010/03/04)
(Chemical Equation Presented) A thermodynamically controlled resolution has allowed for the generation of diastereomerically enriched complexes, by chirality transfer from an enantiopure building block to a dynamically racemic biaryl derivative. A switcha
