119487-81-9

Basic information

• Product Name: [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-hex-5-enyl]-phenyl-amine
• CAS NO: 119487-81-9
• Molecular Weight: 424.007
• Mol File: 119487-81-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-hex-5-enyl]-phenyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-hex-5-enyl]-phenyl-amine(119487-81-9)
• EPA Substance Registry System: [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-hex-5-enyl]-phenyl-amine(119487-81-9)

Safety Data

• Hazardous Substances Data: 119487-81-9(Hazardous Substances Data)

Upstream product

• 24824-93-9 chloromethyl p-tolyl sulfoxide 
• 538-51-2 benzylidene phenylamine 
• 119487-94-4 1-chloro-4-pentenyl p-tolyl sulfoxide 

Downstream Products

• 119487-90-0 (Z)-1,2-diphenyl-3-(3-butenyl)aziridine 
• 119487-85-3 (2R,3R)-2-But-3-enyl-1,3-diphenyl-2-((S)-toluene-4-sulfinyl)-aziridine 
• 119487-85-3 (2R,3R)-2-But-3-enyl-1,3-diphenyl-2-(toluene-4-sulfinyl)-aziridine 

Relevant articles and documents

Stereospecific Desulfinylation of Sulfinylaziridines with Alkylmetals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Studies

Addition of the anion derived from 1-chloroalkyl p-tolyl sulfoxides 3 to N-arylimines 4 afforded chloro amines 5 in high yields with complete 1,2- and 1,3-asymmetric induction.Treatment of these chloro amines 5 with potassium tert-butoxide gave sulfinylaz