119487-89-7

Upstream product

• 119487-84-2 (2R,3R)-1-(4-Bromo-phenyl)-2-decyl-3-phenyl-2-((S)-toluene-4-sulfinyl)-aziridine 
• 780-20-1 N-benzylidene-4-bromoaniline 
• 119487-99-9 (4-Bromo-phenyl)-[(1R,2R)-2-chloro-1-phenyl-2-(toluene-4-sulfinyl)-dodecyl]-amine 
• 122406-36-4 (4-Bromo-phenyl)-[(1R,2R)-2-chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-dodecyl]-amine 
• 119487-99-9 (4-Bromo-phenyl)-[(1R,2R)-2-chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-dodecyl]-amine 
• 119487-84-2 (2R,3R)-1-(4-Bromo-phenyl)-2-decyl-3-phenyl-2-(toluene-4-sulfinyl)-aziridine 
• 116386-54-0 (-)-1-chloroundecyl p-tolyl sulfoxide 

Relevant academic research and scientific papers

Stereospecific Desulfinylation of Sulfinylaziridines with Alkylmetals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Studies

Addition of the anion derived from 1-chloroalkyl p-tolyl sulfoxides 3 to N-arylimines 4 afforded chloro amines 5 in high yields with complete 1,2- and 1,3-asymmetric induction.Treatment of these chloro amines 5 with potassium tert-butoxide gave sulfinylaz

STEREOSPECIFIC DESULFINYLATION OF SULFINYLAZIRIDINES WITH ETHYLMAGNESIUM BROMIDE: A NOVEL SYNTHESIS OF (Z)-N-ARYLAZIRIDINES

A novel synthesis of (Z)-N-arylaziridines was realised by the stereospecific desulfinylation of (E)-(N-aryl)sulfinylaziridines which were synthesized from 1-chloroalkyl p-tolyl sulfoxides and N-arylimines in high yields.