1194952-33-4Relevant articles and documents
Novel 7-(dimethylamino)fluorene-based fluorescent probes and their binding to human serum albumin
Park, Kwanghee Koh,Park, Joon Woo,Hamilton, Andrew D.
, p. 4225 - 4232 (2009)
A novel solvatochromic fluorescent molecule, 9,9-dibutyl-7-(dimethylamino)- 2-fluorenesulfonate 2 was synthesized from 2-nitrofluorene in moderate yield. The fluorescence spectra of 2 and 7-(dimethylamino)-2-fluorenesulfonate 1 shift to shorter wavelength
Preparation method of 2-nitryl-7-acetyloximido-9,9-dibutylfluorene
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Paragraph 0021; 0025; 0026; 0030, (2018/04/01)
The invention relates to a preparation method of 2-nitryl-7-acetyloximido-9,9-dibutylfluorene. The preparation method comprises the following steps: enabling 2-nitrylfluorene and bromobutane to react in the presence of triethylamine and dichloromethane at 33 DEG C to 37 DEG C to obtain a compound 1; enabling the compound 1 and acetyl chloride to react in the presence of the dichloromethane and aluminum trichloride at -5 DEG C to 5 DEG C to prepare a compound 2; enabling the compound 2 and hydroxylamine hydrochloride to be subjected to reflowing reaction in the presence of methanol to prepare the 2-nitryl-7-acetyloximido-9,9-dibutylfluorene. By optimizing a synthetic route, technological conditions and the like, the yield and the purity of the 2-nitryl-7-acetyloximido-9,9-dibutylfluorene are high, so that the 2-nitryl-7-acetyloximido-9,9-dibutylfluorene is suitable for industrial production and is suitable for being used as a photoinitiator of chips of electronic equipment including computers, mobile phones and the like.
NOVEL OXIMESTER FLUORINE COMPOUND, AND PHOTOPOLYMERIZATION INITIATOR AND PHOTORESIST COMPOSITION COMPRISING SAME
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Paragraph 0048-0050, (2015/03/18)
Provided are a novel fluorene oxime ester compound, and a photopolymerization initiator and a photoresist composition containing the same.