119547-77-2Relevant academic research and scientific papers
GENERATION OF SULFUR YLIDES BY THE DESILYLATION OF α-TRIMETHYLSILYLBENZYL SULFONIUM SALTS
Padwa, Albert,Gasdaska, John R.
, p. 4147 - 4156 (2007/10/02)
The -sigmatropic rearrangement of sulfur ylides derived via the desilylation of several α-trimethylsilylbenzyl sulfonium salts has been studied.The initally formed ylide was found to rapidly equilibrate with the thermodynamically more stable ylide.In the absence of trapping reagents, a Sommelet-Hauser type rearrangement occurs.
