1195512-57-2

Basic information

• Product Name: 2-(4-methoxyphenyl)-2-oxoethane-1,1-diyl diacetate
• Synonyms: 2-(4-methoxyphenyl)-2-oxoethane-1,1-diyl diacetate
• CAS NO: 1195512-57-2
• Molecular Weight: 266.251
• Mol File: 1195512-57-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxyphenyl)-2-oxoethane-1,1-diyl diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxyphenyl)-2-oxoethane-1,1-diyl diacetate(1195512-57-2)
• EPA Substance Registry System: 2-(4-methoxyphenyl)-2-oxoethane-1,1-diyl diacetate(1195512-57-2)

Safety Data

• Hazardous Substances Data: 1195512-57-2(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 1076-95-5 p-methoxyphenylglyoxal 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 830-09-1 3-(4'-methoxyphenyl)propenoic acid 

Downstream Products

• 1076-95-5 p-methoxyphenylglyoxal 

Relevant articles and documents

Hypervalent Iodine Mediated C-C Double Bond Activation: A Cascade Access to α-Keto Diacetates from Readily Available Cinnamic Acids

The reaction of cinnamic acids with (diacetoxyiodo)benzene in 1,2-dichloroethane in the presence of sulfuric acid provides an easy and direct access to the α-keto diacetate framework. This hypervalent iodine mediated oxidative reaction involves a tandem sequence of aryl migration, insertion of an oxygen atom, decarboxylation and diacetoxylation. A reaction mechanism is proposed and discussed in light of control experiments.