119554-69-7Relevant academic research and scientific papers
A New Reaction in Organosilicon Chemistry: The Oxidative Ring Closure of Allylsilanes with Ceric Ammonium Nitrate
Wilson, Stephen R.,Augelli-Szafran, Corinne E.
, p. 3983 - 3996 (1988)
Allylsilanes containing heteroatom nucleophiles yield cyclic products when treated with (NH4)2Ce(NO3)6.For example, hydroxy and amido-containing allylsilanes yield the corresponding tetrahydrofuran, tetrahydropyran, and piperidine analogs.These reactions and their application to natural product synthesis will be discussed.
