Tetrahedron p. 3983 - 3996 (1988)
Update date:2022-08-04
Topics:
Wilson, Stephen R.
Augelli-Szafran, Corinne E.
Allylsilanes containing heteroatom nucleophiles yield cyclic products when treated with (NH4)2Ce(NO3)6.For example, hydroxy and amido-containing allylsilanes yield the corresponding tetrahydrofuran, tetrahydropyran, and piperidine analogs.These reactions and their application to natural product synthesis will be discussed.
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