119555-54-3Relevant academic research and scientific papers
A NOVEL PREPARATION OF 3-METHYLTHIO-2-OXOPROPANAL ACETALS USING METHYLTHIOMETHYL p-TOLYL SULFONE
Ogura, Katsuyuki,Uchida, Tohru,Tsuruda, Toshihiko,Takahashi, Kazumasa
, p. 5703 - 5706 (2007/10/02)
Treatment of an alkoxyacetyl derivative (3) of methylthiomethyl p-tolyl sulfone (1), easily obtainable from an alkoxyacetic ester and 1, with such a base as triethylamine or DABCO affords 3-methylthio-2-oxopropanal acetal (4).
A VERSATILE REAGENT FOR SYNTHESIS OF α-HYDROXY ALDEHYDES AND KETONES --- METHYLTHIOMETHYL p-TOLYL SULFONE
Ogura, Katsuyuki,Tsuruda, Toshihiko,Takahashi, Kazumasa,Iida, Hirotada
, p. 3665 - 3668 (2007/10/02)
Methylthiomethyl p-tolyl sulfone (1) can be utilized for synthesizing α-hydroxy ketones as well as α-hydroxy aldehydes, the hydroxyl group of which is protected with acetyl, tetrahydropyranyl, or methoxymethyl group.
