1196062-34-6

Basic information

• Product Name: 2-(p-MeC₆H₄NPPh₂)-6-MeC₅H₃N
• Synonyms: 2-(p-MeC₆H₄NPPh₂)-6-MeC₅H₃N
• CAS NO: 1196062-34-6
• Molecular Weight: 382.445
• Mol File: 1196062-34-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(p-MeC₆H₄NPPh₂)-6-MeC₅H₃N(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(p-MeC₆H₄NPPh₂)-6-MeC₅H₃N(1196062-34-6)
• EPA Substance Registry System: 2-(p-MeC₆H₄NPPh₂)-6-MeC₅H₃N(1196062-34-6)

Safety Data

• Hazardous Substances Data: 1196062-34-6(Hazardous Substances Data)

Upstream product

• 2101-86-2 p-methylazidobenzene 
• 132682-77-0 diphenyl-(6-methyl-pyridin-2-yl)phosphine 

Downstream Products

• 1196062-37-9 2-(p-MeC₆H₄NPPh₂)-6-(CH₂PPh₂)C₅H₃N 

Relevant articles and documents

Synthesis and characterization of Sn(II), Pb(II) and Yb(II) complexes supported by [C(Ph2PNSiMe3){6-(2-RC5H 3N)}]2- or [CH(Ph2PNSiMe3){6-(2- RC5H3N)}]- (R = 3,5-dimethyl-1-pyrazolyl or iminophosphoranyl) ligands

The synthesis and characterization of several tin(II), lead(II) and ytterbium(II) complexes supported by [C(Ph2PNSiMe3){6-(2- RC5H3N)}]2- or [CH(Ph2PNSiMe 3){6-(2-RC5H3N)}]- (R = 3,5-dimethyl-1-pyrazolyl or iminophosphoranyl) ligands are reported. Reaction of 2-R-6-{CH2P(Ph2)NSiMe3}C5H 3N with M[N(SiMe3)2]2 (M = Sn, Pb) generated tin(II) and lead(II) complexes [M{C(Ph2PNSiMe 3){6-(2-RC5H3N)}}]2 [3, M = Sn, R = 3,5-dimethyl-1-pyrazolyl; 4, M = Pb, R = 3,5-dimethyl-1-pyrazolyl; 9, M = Sn, R = Me3SiNP(Ph2); 10, M = Pb, R = Me3SiNP(Ph 2)]. When R = p-MeC6H4NP(Ph2), a N,N-chelate tin(II) complex, [Sn{2-{N(p-MeC6H4)PPh 2}-6-{CHP(Ph2)NSiMe3}}{N(SiMe3) 2}] (11), was isolated. Treatment of 2-(Ph2PNSiMe 3)-6-{CH2P(Ph2)NSiMe3}C 5H3N with Yb[N(SiMe3)2] 2(DME) afforded N,N,N-chelale ytterbium(II) complex [Yb{2-{N(SiMe3)PPh2}-6-{CHP(Ph2)NSiMe 3}}{N(SiMe3)2}] (12). The complexes were characterized by elemental analyses and multinuclear NMR spectroscopy. Complexes 3, 4 and 10-12 were further characterized by single crystal X-ray diffraction techniques.