119612-75-8Relevant academic research and scientific papers
ENOLATE IONS: SYNTHETIC EQUIVALENTS OF 1,3-DIANIONS. CONVENIENT SYNTHESIS OF SUBSTITUTED 3,4-DIHYDRO-5-OXO-2H,5H-PYRANOPYRANS
Saalfrank, Rolf W.,Hanek, Martin
, p. 4787 - 4792 (1988)
Our investigations on tetradonor-subtituted allenes prompted us to use enolate ions and trimethylsilyl enol ethers as 1,3-dianion equivalents.- A mixture of chloro(trimethyl)silane and cyclobutane-1,1-dicarboxylic acid dichloride (6) reacts with enolates
Enolate Ions, II. - Convenient Synthesis of 3,4-Dihydro-2,4-dioxo-2H-pyrans and 2-Pyrones. - Enolate Ions as Synthetic Equivalents of 1,3-Dianions. - Crystal and Molecular Structure of Ethyl 6-Ethoxy-3,4-dihydro-3,3-dimethyl-2,4-dioxo-2H-pyran-5-carboxyla
Saalfrank, Rolf W.,Guendel, Juergen,Rossmann, Guenther,Hanek, Martin,Rost, Walter,et al.
, p. 1175 - 1183 (2007/10/02)
Reaction of dimethylmalonyl chloride (6a) or cyclic 1,1-dicarbonyl dichlorides 6b-d with two equivalents of lithium enolates 7, 22, and silyl enol ethers 8, respectively, yields 3,4-dihydro-2,4-dioxo-2H-pyrans 10, 24, or spiro compounds 11-13, 25-27.The s
