ENOLATE IONS: SYNTHETIC EQUIVALENTS OF 1,3-DIANIONS. CONVENIENT SYNTHESIS OF SUBSTITUTED 3,4-DIHYDRO-5-OXO-2H,5H-PYRANOPYRANS

DOI: 10.1016/S0040-4020(01)86181-0

Source and publish data:

Tetrahedron p. 4787 - 4792 (1988)

Update date:2022-07-31

Topics:

Authors:

Saalfrank, Rolf W.

Hanek, Martin

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Article abstract of DOI:10.1016/S0040-4020(01)86181-0

Our investigations on tetradonor-subtituted allenes prompted us to use enolate ions and trimethylsilyl enol ethers as 1,3-dianion equivalents.- A mixture of chloro(trimethyl)silane and cyclobutane-1,1-dicarboxylic acid dichloride (6) reacts with enolates

Full text of DOI:10.1016/S0040-4020(01)86181-0

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