119613-01-3

Upstream product

• 119612-97-4 N-(2-Methoxy-phenyl)-N'-p-tolyl-diazene N-oxide 
• 119612-98-5 N-(2-Methoxy-phenyl)-N'-p-tolyl-diazene N'-oxide 

Relevant academic research and scientific papers

Facile Photorearrangement of Some Crowded Azoxyarenes via Two Concurrent Pathways

Naphthalene-1-ONN-azoxybenzenes and some unsymmetrically ortho-substituted ONN- and NNO-azoxybenzenes were prepared, and their photochemical behavior in ethanol was compared.The crowded azoxyarenes tend to undergo a facile Wallach rearrangement via the known azoxy-ortho oxygen migration and a concurrent pathway involving ONN-NNO-isomerization.The relative contribution of the two pathways was affected by substituents.