Bulletin of the Chemical Society of Japan p. 3005 - 3007 (1988)
Update date:2022-08-03
Topics:
Okubo, Masao
Hyakutake, Hayato
Taniguchi, Naoki
Naphthalene-1-ONN-azoxybenzenes and some unsymmetrically ortho-substituted ONN- and NNO-azoxybenzenes were prepared, and their photochemical behavior in ethanol was compared.The crowded azoxyarenes tend to undergo a facile Wallach rearrangement via the known azoxy-ortho oxygen migration and a concurrent pathway involving ONN-NNO-isomerization.The relative contribution of the two pathways was affected by substituents.
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