119615-25-7Relevant academic research and scientific papers
Eine allgemeine, einfache und schonende Synthesemethode fuer Fluororganylborane
Bir, Gerd,Schacht, Wolfgang,Kaufmann, Dieter
, p. 267 - 272 (1988)
The fluorination of a number of alkyl- and arylchloro- and bromoboranes succeeds upon transhalogenation with lithium or potassium fluoride under mild reaction conditions in good yields.
A New Borylation Method for Alkylbenzene and Polystyrene
Paetzold, Peter,Hoffmann, Juergen
, p. 3724 - 3733 (2007/10/02)
The borylation of alkylbenzenes by Hal2BH (Hal = F, Cl, Br) gives H2 and a mixture of m- and p-alkyl(dihaloboryl)benzenes.In the case of bulky alkyl groups, such as isopropyl, tert-butyl, these are partially split off as R - H and RBHal2.The phenyl groups in polystyrene-divinylbenzene copolymers undergo borylation with Br2BH in a 55percent yield.
