119616-49-8Relevant academic research and scientific papers
The total synthesis of avermectin A(1a)
Danishefsky,Armistead,Wincott,Selnick,Hungate
, p. 2967 - 2980 (1989)
Key fragments for the total synthesis of the title compound were elaborated from D-ribose and D-glucose and coupled through a crossed aldol dehydration maneuver (33 + 44→46). An intramolecular variant of the Nozaki reaction (47→48) led to the all-critical
