119654-82-9

Basic information

• Product Name: Co(CO)(dppe)2(PF₆)
• CAS NO: 119654-82-9
• Molecular Weight: 1028.82
• Mol File: 119654-82-9.mol

Chemical Properties

• CAS DataBase Reference: Co(CO)(dppe)2(PF₆)(CAS DataBase Reference)
• NIST Chemistry Reference: Co(CO)(dppe)2(PF₆)(119654-82-9)
• EPA Substance Registry System: Co(CO)(dppe)2(PF₆)(119654-82-9)

Safety Data

• Hazardous Substances Data: 119654-82-9(Hazardous Substances Data)

Upstream product

• 71-48-7 cobalt(II) acetate 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Relevant articles and documents

Sensitized photoreduction of cobalt(II) and iron(II). Structural characterization of 2)2PF6

Triplet-state ketones readily sensitized the photoreduction of bis(acetylacetonato)cobalt(II) or Cosolv2+ under atmospheric pressure of carbon monoxide to give Co(CO)4-.The low-valent cobalt could be trapped and isolated as phosphine-substituted metal carbonyl complexes.The crystal structure of one of the products, 2)2>PF6 has been determined.It is orthorhombic, space group Pbca, Z=8, with unit cell dimensions a 19.704(5), b 24.850(13), c 21.865(9) Angstroem.Phosphine-substituted iron(0) carbonyl complexes have also been isolated from similar photoreductions of iron(II) species.