Journal of Organometallic Chemistry p. C17 - C21 (1989)
Update date:2022-07-29
Topics:
Lin, Jiann T.
Wang, Shiow Y.
Yeh, Show K.
Chow, Yuan L.
Triplet-state ketones readily sensitized the photoreduction of bis(acetylacetonato)cobalt(II) or Cosolv2+ under atmospheric pressure of carbon monoxide to give Co(CO)4-.The low-valent cobalt could be trapped and isolated as phosphine-substituted metal carbonyl complexes.The crystal structure of one of the products, a 19.704(5), b 24.850(13), c 21.865(9) Angstroem.Phosphine-substituted iron(0) carbonyl complexes have also been isolated from similar photoreductions of iron(II) species.
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