119711-72-7Relevant academic research and scientific papers
Approaches to the total synthesis of phomactins
Balnaves, Andrew S.,McGowan, Graham,Shapland, Peter D. P.,Thomas, Eric J.
, p. 2713 - 2716 (2003)
The macrocyclic triene 34, an advanced intermediate for synthesis of phomactins, has been synthesized using the 2,3-Wittig rearrangement of the propargylic ether 21 as a key step.
1,4-Cyclohexadienes as mechanistic probes for the Jacobsen epoxidation: Evidence for radical pathways
Engelhardt, Ulrike,Linker, Torsten
, p. 1152 - 1154 (2005)
1,4-Cyclohexadienes allow a direct comparison of epoxidation and C-H oxidation within the same molecule and give evidence for radical pathways during the Jacobsen epoxidation. The Royal Society of Chemistry 2005.
Synthesis of precursors of phomactins using [2,3]-Wittig rearrangements
Shapland, Peter D.P.,Thomas, Eric J.
experimental part, p. 4201 - 4211 (2009/09/27)
o-Toluic acid has been converted into methyl (8RS,9SR)-7-(bromomethyl)-8,9-dimethyl-1,4-dioxaspiro[4.5]dec-6-ene-8-carboxylate, the stereochemical defining step being a conjugate addition of lithium dimethylcuprate to a cyclohexadienone prepared using a B
AN IMPROVED PROCEDURE FOR THE CONVERSION OF 3,3-DISUBSTITUTED-1,4-CYCLOHEXADIENES TO 2,5-CYCLOHEXADIEN-1-ONES
Schultz, Arthur G.,Taveras, Arthur G.,Harrington, Roger E.
, p. 3907 - 3910 (2007/10/02)
The bis-allylic oxidations of 1,4-cyclohexadienes with tert-butyl hydroperoxide and pyridinium dichromate give 2,5-cyclohexadien-1-ones in good to excellent yields.
