119754-26-6Relevant academic research and scientific papers
Lanthanide triple-stranded helical complexes with a substituted 2,6-pyridinedicarboxylate
Platas-Iglesias,Piguet,Andre,Buenzli
, p. 3084 - 3091 (2001)
A 4-aminophenylethynyl substituent has been grafted into the 4-position of the pyridine ring in dipicolinic acid to yield ligand L4 the pKa's of which are 8.77(5), 3.54(3), 2.58(1) and 1.01(3). Ligand L4 reacts with trival
Synthesis of Some Substituted Dimethyl and Diethyl 4-(Phenylethynyl)-2,6-pyridinedicarboxylates
Takalo, Harri,Kankare, Jouko,Haenninen, Elina
, p. 448 - 454 (2007/10/02)
Substituted dimethyl and diethyl 4-(phenylethynyl)-2,6-pyridinedicarboxylates were prepared by coupling reactions between dialkyl 4-halo-2,6-pyridinedicarboxylates and terminal arylacetylenes in the presence of an organopalladium catalyst and copper(I) iodide in a suitable solvent system.The terminal acetylenes needed in this work were synthesized from the corresponding aryl halides using either (trimethylsilyl)acetylene or 2-methyl-3-butyn-2-ol followed by deprotection of the triple bond, depending on the nature of the compound in question.
