1198-62-5Relevant academic research and scientific papers
Organofluorine sulfur-containing compounds: V. Joint pyrolysis with chlorine or bromine of polyfluoroarenethioles, polyfluorohetarenethioles, and their derivatives
Platonov,Maksimov,Dvornikova,Nikul'shin
, p. 1647 - 1653 (2005)
Joint pyrolysis with chlorine and bromine of polyfluoroarenethiols, -hetarenethiols, and their derivatives at 300-650°C furnished polyfluorocompounds containing chlorine and bromine. 2005 Pleiades Publishing, Inc.
Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5
Nikul'shin,Maksimov,Platonov
, p. 200 - 205 (2016)
Replacement of the thiol group in polyfluoroarenethiols with chlorine was performed by treating with PCl5 as chlorinating agent. By heating in ampules at 200-220°C polyfluoro- and polyfluorochloroarenethiols with PCl5 mono- and dichloropolyfluoroarenes and also 1,2,4-trifluorotrichlorobenzene were synthesized. Dichloropolyfluoroarenes contain chlorine atoms in ortho- and para-positions.
Synergism in catalytic halogen-exchange fluorination of 4-chloronitro- and dichlorotetrafluorobenzenes
Shipilov,Bykova,Elokhova,Igumnov
, p. 487 - 491 (2007/10/03)
Synergism was studied in catalytic halogen-exchange fluorination of 4-chloronitro- and dichlorotetrafluorobenzenes. The synergistic effect in the fluorination of chloroaromatic compounds with potassium fluoride was mainly attributed to separation of the activation functions of catalysts with respect to substrate molecules.
Catalytic and noncatalytic ammonolysis of polyfluorinated 1,3-dichlorobenzenes
Selivanova,Pokrovskii,Shteingarts
, p. 1023 - 1029 (2007/10/03)
Reactions of 1,3-dichlorotetrafluorobenzene and 1,3-dichloro-2,4,6-trifluorobenzene with aqueous ammonia in the presence and in the absence of copper(I) salt lead to fluorine replacement by amino group in the para and ortho positions with respect to the chlorine atom. Ammonolysis of the resulting chloropolyfluoroanilines in the absence of a catalyst involves replacement of fluorine atom in the meta position with respect to the amino group. In the presence of copper(I) salt, catalytic aminodechlorination occurs at the para and ortho positions with respect to the amino group introduced in the first stage.
Catalytic fluorination of hexachlorobenzene with supported potassium fluoride
Shipilov,Fedoseev
, p. 556 - 557 (2007/10/03)
Fluorination of hexachlorobenzene with potassium fluoride supported on calcium fluoride or barium fluoride with using quaternary phosphonium salt as a phase-transfer catalyst was studied, and a synergism was observed.
Thermolytic transformations of polyfluoroorganic compounds 31. Copyrolysis of 4-chlorotetrafluorobenzo trichloride with chlorodifluoromethane
Dvornikiva, K. V.,Platonov, V. E.
, p. 2079 - 2082 (2007/10/02)
Copyrolysis of 4-chlorotetrafluorobenzotrichloride with chlorodifluoromethane (as the source of difluorocarbene) gave 4-chlorodifluoromethyl-α-chlorohexafluorostyrene, 1,4-dichlorotetrafluorobenzene, and 4-(chlorodifluoromethyl)chlorotetrafluorobenzene along with 4-chloro-α-chlorohexafluorostyrene.Poissible routes for the formation of these products have been offered. - Key words: copyrolysis; 4-chloro-α-chlorohexafluorostyrene; 4-chlorodifluoromethyl-α-chlorohexafluorostyrene; difluorocarbene; polychlorofluorocyclohexadienes.
PREPARATION OF POLYFLUOROBENZOTRIHALIDES BY THE REACTIONS OF OCTAFLUOROTOLUENE AND ITS DERIVATIVES WITH ALUMINUM HALIDES. SYNTHESIS OF POLYFLUOROSTILBENES AND DECAFLUOROTOLAN
Dvornikova, K. V.,Platonov, V. E.,Yakobson, G. G.
, p. 525 - 532 (2007/10/02)
Reactions of some polyfluoro aromatic compounds containing a CF3 group with aluminum halides (AlCl3, AlBr3) were studied.In these reactions there occurs the replacement of fluorine atoms by chlorine or bromine both in the side chain in aromatic ring.Treat
