1198587-49-3

Upstream product

• 75-52-5 nitromethane 
• 1198587-40-4 methyl 2-O-benzyl-3,4-dideoxy-4-(4-methylphenyl)sulfonyl-6-O-mesyl-α-D-erythro-hex-3-enopyranoside 
• 1198587-45-9 methyl 2-O-benzyl-3-C-nitromethyl-4-(4-methylphenyl)sulfonyl-6-O-triphenylmethyl-α-D-glucopyranoside 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 1198587-50-6 methyl 2-O-benzyl-4,6-cyclo-3-C-nitromethyl-4-(4-methylphenyl)sulfonyl-3,4,6-trideoxy-α-D-glucopyranoside 

Relevant academic research and scientific papers

Vinyl sulfone modified hex-3-enopyranosides: novel routes to C3-C4 and C4-C5 cyclopropanated pyranosides

In a departure from metal-based cyclopropanation reactions, 4-sulfon.ylhex-3-ernopyranosides carrying a leaving group at either of the two γ-positions are used as efficient intermediates for the synthesis of C3-C4 and C4-C5 cyclopropanated pyranosides.