119861-75-5

Upstream product

• 89232-37-1 {Ir(1,5-cyclooctadiene)(η2-(o-bromophenyl)diphenylphosphine)}SbF6 
• 75-05-8 acetonitrile 

Downstream Products

• 89232-37-1 {Ir(1,5-cyclooctadiene)(η2-(o-bromophenyl)diphenylphosphine)}SbF6 
• 89232-35-9 {Ir(1,5-cyclooctadiene)(η1-(o-bromophenyl)diphenylphosphine)Cl} 

Relevant academic research and scientific papers

Halocarbon binding in [Ir(cod)(η2-o-BrC6H4PPh 2)]SbF6

In the complex [Ir(cod)(η2-L)]SbF6 (2, L = o-BrC6H4PPh2), L chelates to Ir via P and the Br bound to the aromatic ring. Complex 2 was formed from Ir-(cod)(η1-L)Cl (1) with AgSbF6. 2 reacts with Cl- to give 1, with MeCN to give [Ir(cod)(MeCN)(η1-L)]SbF6 reversibly, and with H2 to give [IrH2(cod)(η2-L)]SbF6, a hydrogenation catalyst.