119873-30-2

Upstream product

• 119873-15-3 (R)-3-(2-Amino-phenylsulfanyl)-butyric acid methyl ester 
• 623-43-8 crotonic acid methyl ester 
• 108-98-5 thiophenol 
• 119943-70-3 (R)-3-(2-Nitro-phenylsulfanyl)-butyric acid 
• 119873-07-3 (R)-3-(2-Nitro-phenylsulfanyl)-butyric acid methyl ester 
• 98186-14-2 3-(2-Nitro-phenylsulfanyl)-butyric acid 
• 67-56-1 methanol 
• 1443455-88-6 (R)-1,1,1,3,3,3-hexafluoropropan-2-yl 3-(phenylthio)butanoate 

Relevant academic research and scientific papers

Organocatalytic asymmetric sulfa-michael addition of thiols to α,β-unsaturated hexafluoroisopropyl esters: Expeditious access to (R)-thiazesim

A highly efficient organocatalytic asymmetric SMA reaction of hexafluoroisopropyl α,β-unsaturated esters has been developed. Introducing electron-withdrawing hexafluoroisopropyl ester is crucial to enhancing the electrophilicity of unsaturated esters as S

Structural requirements of a chiral ligand for the catalytic asymmetric addition of thiophenol to α,β-unsaturated esters

The tridentate amino ether ligands 1 and 14 were developed through systematic structural modification of the bidentate diether ligand 2. The reaction of thiophenol with methyl crotonate was catalyzed by 14 and lithium thiophenolate to afford (S)-methyl 3-

Oxazepines and Thiazepines. XIX Synthesis of Optically Active 2,3-Dihydro-1,5-benzothiazepin-4(5H)-ones

Optically active 2,3-dihydro-1,5-benzothiazepin-4(5H)-ones (14-17) have been synthesized via resolution and chemical transformation of nitrocarboxylic acids 6-9.Starting from the latter various optically active substances have been synthesized as well.Optical purity was checked by NMR spectroscopy. - Keywords: Resolution; Optical purity; Optically active benzothiazepines