119877-85-9Relevant academic research and scientific papers
Metacyclophanes and Related Compounds. 24. Preparation and Reaction of Trimethyl- and Tetramethylmetacyclophane
Tashiro, Masashi,Watanabe, Tetsuya,Tsuge, Akihiko,Sawada, Tsuyoshi,Mataka, Shuntaro
, p. 2632 - 2638 (1989)
8,16,24,32-Tetramethyl- and 8,16,24-trimethylmetacyclophane (9 and 10) were prepared by using the tert-butyl group as a positional protective group.Friedel-Crafts acylation of 9 and 10 afforded the corresponding ketones, 12 and 13, respect
