Metacyclophanes and Related Compounds. 24. Preparation and Reaction of Trimethyl- and Tetramethylmetacyclophane

DOI: 10.1021/jo00272a034

Source and publish data:

Journal of Organic Chemistry p. 2632 - 2638 (1989)

Update date:2022-08-03

Topics:

Authors:

Tashiro, Masashi

Watanabe, Tetsuya

Tsuge, Akihiko

Sawada, Tsuyoshi

Mataka, Shuntaro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00272a034

8,16,24,32-Tetramethyl<2.2.2.2>- and 8,16,24-trimethyl<2.2.2>metacyclophane (9 and 10) were prepared by using the tert-butyl group as a positional protective group.Friedel-Crafts acylation of 9 and 10 afforded the corresponding ketones, 12 and 13, respect

Full text of DOI:10.1021/jo00272a034

Products guided by the article

Product name:Benzenemethanethiol, 3,3'-(1,2-ethanediyl)bis[5-(1,1-dimethylethyl)-2-methyl-

Cas No:119877-85-9

R&D Labs maybe for 119877-85-9

Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Nanjing Qirui Material Co., Ltd.

Contact:+86-25-52320053

Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
CGeneTech (Suzhou, China) Co., Ltd.

Contact:+86-512-62956962

Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
ShangHai Soyoung Biotechnology Inc

website:http://www.soyoungbio.com

Contact:+86-21-69893009

Address:shanghai

Relevant to this article

Cyclopentannulation by an iterative process of sequential Claisen rearrangement and enyne radical closure: Routes to triquinane and propellane systems and use in the synthesis of (±)-ceratopicanol

Doi:10.1021/jo951930h
(1996)
Synthesis and spectroscopic studies of new hydridoruthenium complexes: Catalytic reactions of [RuHCl(bpzm)(cod)] (bpzm = bis(pyrazol-1-yl) methane, cod = cycloocta-1,5-diene)

Doi:10.1016/0022-328X(95)05836-E
(1996)
Discovery of 2-aminothiazole-4-carboxamides, a novel class of muscarinic M₃ selective antagonists, through solution-phase parallel synthesis

Doi:10.1248/cpb.53.437
(2005)
3-Carboxypyridinium chlorochromate - aluminium chloride - An efficient and inexpensive reagent system for the selective oxidation of sulfides to sulfoxides and sulfones in solution and under microwave irradiation

Doi:10.1139/v05-008
(2005)
A stereoselective synthesis of dinucleotide phosphorothioates, using chiral phosphoramidites as intermediates

Doi:10.1016/0040-4039(95)02355-0
(1996)
The First L-Iduronic Acid-Type 1-N-Iminosugars Having Inhibitory Activity of Experimental Metastasis

Doi:10.1021/ja953989b
(1996)

Article Doi