119897-90-4Relevant academic research and scientific papers
Asymmetric silyl nitronate cycloadditions with bornane-10,2-sultam derivatives
Kim,Lee
, p. 1359 - 1370 (1991)
Asymmetric silyl nitronate cycloadditions with N-acryloyl (2R)-bornane-10,2-sultam, N-acryloyl (2S)-bornane-10,2-sultam, and N-methacryloyl (2R)-bornane-10,2-sultam have been studied. The asymmetric silyl nitronate cycloaddition/elimination methodology pr
The Preparation of Optically Active Δ2-Isoxazolines. A Model for Asymmetric Induction in the Non Lewis Acid Catalyzed Reactions of Oppolzer's Chiral Sultam
Curran, Dennis P.,Kim, Byeang Hyean,Daugherty, James,Heffner, Timothy, A.
, p. 3555 - 3558 (2007/10/02)
Good diastereoselectivity (ca. 90/10) is reported in the cycloaddition reactions of Oppolzer's chiral sultam with nitrile oxides.A model is proposed which may apply to other non Lewis acid promoted reactions of this sultam.
