142011-79-8

Upstream product

• 142011-75-4 (R)-5-((tert-butyldimethylsilyl)oxy)-4-hydroxypentan-2-one 
• 142011-77-6 tert-Butyl-dimethyl-((4R,6R)-2,2,6-trimethyl-[1,3]dioxan-4-ylmethoxy)-silane 
• 142011-74-3 (R)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methyl-4,5-dihydro-isoxazole 
• 142011-76-5 (2R,4R)-1-(tert-Butyl-dimethyl-silanyloxy)-pentane-2,4-diol 
• 119897-90-4 (5R)-5-hydroxymethyl-3-methyl-2-isoxazoline 
• 223131-83-7 (E)-4-hydroxy-6-phenylhex-5-en-2-one 
• 124781-43-7 (E)-6-phenylhex-5-ene-2,4-diol 
• 905588-05-8 (2R,4R,5E)-6-phenylhex-5-ene-2,4-diyl diacetate 
• 905588-08-1 (2R,4R,5E)-6-phenylhex-5-ene-2,4-diol 
• 905588-29-6 (4R,6R,E)-2,2,4-trimethyl-6-styryl-1,3-dioxane 
• 905588-35-4 (4R,6R)-2,2,6-trimethyl-1,3-dioxane-4-carbaldehyde 
• 142011-78-7 ((4R,6R)-2,2,6-trimethyl-1,3-dioxan-4-yl)methanol 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant academic research and scientific papers

Enantioselective syntheses of (+)-methyl nonactate and (-)-methyl 8-epi-nonactate via asymmetric cycloadditive route

Enantioselective routes to (+)-methyl nonactate (2 and (-)-methyl 8-epi-nonactate (3) are described. The cornerstone of this synthetic strategy is a combination of asymmetric silyl nitronate cycloaddition and asymmetric reduction, which provides the key s

Enzymatic approach to enantiomerically pure 5-alken-2,4-diols and 4-hydroxy-5-alken-2-ones: Application to the synthesis of chiral synthons

Enantiomerically pure 1,3-diols 1-3 were obtained by a chemoenzymatic approach (lipase PS from Burkholderia cepacia). These diols were converted into useful chiral synthons, which could be considered homologues of glyceraldehyde and glyceric acid acetonid