119910-79-1Relevant academic research and scientific papers
Switching of the Reaction Pathway for /- and -Witting Rearrangements of 3-Aryl-2-propenyl Propargyl Ethers
Hayakawa, Kenji,Hayashida, Ayumi,Kanematsu, Ken
, p. 1108 - 1110 (1988)
3-Aryl-2-propenyl propargyl ethers (1) undergo the (and ) sigmatropic rearrangement periselectively on treatment with BunLi at-78 deg C, whereas the silylated derivatives (2) perform exclusively the -Wittig rearrangement.
