119968-36-4Relevant academic research and scientific papers
Hexafluoroisopropanol as a unique solvent for stereoselective lododesilylation of vinylsilanes
Ilardi, Elizabeth A.,Stivala, Craig E.,Zakarian, Armen
supporting information; experimental part, p. 1727 - 1730 (2009/04/10)
Stereoselective preparation of iodoalkenes from vinylsilanes is described. 1,1,1,3,3,3-Hexafluoroisopropanol serves as a unique solvent that ensures high yields and stereoselectivities in the iododesilylation of a variety of functionalized substrates.
ORGANIC SYNTHESIS WITH REAGENTS DERIVED FROM 3R3SiMgMe AND MnCl2
Fugami, Keigo,Hibino, Jun-ichi,Nakatsukasa, Shigeki,Matsubara, Seijiro,Oshima, Koichiro,et al.
, p. 4277 - 4292 (2007/10/02)
Synthetically useful reactions mediated by reagents derived from 3 equiv. of R3SiMgMe and MnCl2 are disclosed. (1) The manganese species reacted with terminal acetylenes to give 1,2-disilylated 1-alkenes.Mono- and bis(trimethylsilyl)acetylenes gave tri- a
