119973-55-6Relevant articles and documents
Structure-Dependent Nickel-Catalysed Transposition of N -Allylamides to E- or Z-Enamides
Weber, Felicia,Steinlandt, Philipp S.,Ballmann, Monika,Hilt, Gerhard
, p. 440 - 450 (2016/12/24)
The nickel-catalysed transposition of a carbon-carbon double bond of N-allyl and N-homoallyl amides is described. While the transposition of acyclic amides gave very high Z-selectivity of the enamides, corresponding cyclic N-allyl amides led exclusively t
Nickel-Catalyzed Synthesis of Enamides and Enecarbamates via Isomerization of Allylamides and Allylcarbamates
Halli, Juliette,Kramer, Philipp,Bechthold, Maren,Manolikakes, Georg
supporting information, p. 3321 - 3324 (2015/11/03)
A single-component, air-stable nickel precatalyst can catalyze the isomerization of allylamides for the synthesis of enamides. The scope of the reaction encompasses various substituted allylamides and allylcarbamates as well as homoallylamides. The reaction can be performed on a multigram-scale without specialized glove-box equipment or Schlenk techniques.
Easy access to enamides: A mild nickel-catalysed alkene isomerization of allylamides
Wang, Lu,Liu, Chao,Bai, Ruopeng,Pan, Yani,Lei, Aiwen
supporting information, p. 7923 - 7925 (2013/09/02)
The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an i
