78888-18-3

Basic information

• Product Name: TERT-BUTYL N-ALLYLCARBAMATE
• Synonyms: ALLYL-CARBAMIC ACID TERT-BUTYL ESTER;TERT-BUTYL N-ALLYLCARBAMATE;N-ALLYL-T-BUTYLCARBAMATE;Carbamic acid, 2-propenyl-, 1,1-dimethylethyl ester (9CI);3-(tert-Butoxycarbonylamino)-1-propene;N-(tert-Butyloxycarbonyl)-2-propene-1-amine;N-Allylcarbamic acid tert-butyl ester;tert-Butoxycarbonylallylamine
• CAS NO: 78888-18-3
• Molecular Formula: C₈H₁₅NO₂
• Molecular Weight: 157.21
• Product Categories: N-BOC;Allyl Monomers;Monomers;Polymer Science
• Mol File: 78888-18-3.mol
• Article Data: 2

Chemical Properties

• Melting Point: 36-38 °C(lit.)
• Boiling Point: 48-50°C/0.3mm
• Flash Point: 175 °F
• Appearance: Colorless/Low Melting Solid
• Density: 0.938 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.128mmHg at 25°C
• Refractive Index: 1.4720 (estimate)
• Storage Temp.: Inert atmosphere,Room Temperature
• PKA: 12.60±0.46(Predicted)
• Water Solubility: Insoluble in water. Soluble in methanol.
• CAS DataBase Reference: TERT-BUTYL N-ALLYLCARBAMATE(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-BUTYL N-ALLYLCARBAMATE(78888-18-3)
• EPA Substance Registry System: TERT-BUTYL N-ALLYLCARBAMATE(78888-18-3)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 22-36/37/38
• Safety Statements: 22-26-36/37/39
• RIDADR: UN 1325 4.1/PG 2
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 78888-18-3(Hazardous Substances Data)

Usage

Chemical Properties

white solid crystalline

Uses

tert-Butyl N-allylcarbamate is used in the synthesis of isoxazolidines. Synthesis of 5-substituted thiazolidin-2-ones is from the reaction of xanthates and tert-butyl N-allylcarbamates .

InChI:InChI=1/C8H15NO2/c1-5-6-9-7(10)11-8(2,3)4/h5H,1,6H2,2-4H3,(H,9,10)

Upstream product

• 75-09-2 dichloromethane 
• 107-11-9 1-amino-2-propene 

Downstream Products

• 371252-50-5 pent-2-enylcarbamic acid tert-butyl ester 
• 147410-35-3 tert-butyl (3-(o-tolyl)propyl)carbamate 
• 872214-99-8 tert-butyl 3-(4-fluorophenyl)propylcarbamate 
• 942056-42-0 tert-butyl allyl[2-oxo-3-(triphenyl-λ⁵-phosphoranylidene)prop-1-yl]carbamate 
• 73286-70-1 N-(tert-butoxycarbonyl)-3-pyrroline 
• 115393-77-6 tert-butyl (S)-2-vinylpyrrolidine-1-carboxylate 
• 139200-38-7 tert-butyl N-[(2E)-3-(4-nitrophenyl)prop-2-en-1-yl]carbamate 
• 147528-20-9 N-(tert-butoxycarbonyl)-N-allyl-3-amino-1-propyne 
• 1078123-29-1 tert-butyl N-[1-(2,4,6-trimethoxyphenyl)propyl]carbamate 
• 170384-29-9 (+/-)-1-(N-tert-Butoxycarbonylamino)propan-2-one 

Relevant articles and documents

Phenyl, trihalomethyl or heteroaryl sulfoxides having a latent allyl group bound to sulfur as enzyme inhibitors

Organic sulfoxides having a latent allyl group bound to the sulfur are enzyme inhibitors of the suicide or Kcat type.